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4.4.1.1 · 4.4.1.2 7.2 · 7.3
AQA GCSE Physics · Topic 4.4 Atomic structure
Edexcel International GCSE Physics · Section 7 Radioactivity and particles

The Structure of an Atom, Isotopes and Ions

In this lesson you'll learn to: describe what an atom is made of and how big it is, work out protons, neutrons and electrons from the mass number and atomic number, explain why an atom is neutral but an ion is not, say what makes two atoms isotopes, and describe how electrons move between energy levels by absorbing or emitting electromagnetic radiation.
In this lesson you'll learn to: describe what an atom is made of, write and read symbols like ¹⁴₆C, work out protons, neutrons and electrons from the mass (nucleon) number and atomic (proton) number, explain why an atom is neutral but an ion is not, and say what makes two atoms isotopes.
▶ Prefer to watch? Scroll to the bottom for the video on this topic ▶ A video walkthrough is coming soon — it will appear at the bottom of this page
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Start here — have a play

Don't read anything yet. On tab 1, build carbon-12: pick up a particle, then click the nucleus or a shell to put it there. Watch the symbol build itself as you go, then switch to carbon-14 and see what changes. On tab 2, fire a photon at the electron. On tab 3, find out how much every atom diagram you have ever seen is lying to you.

Build
Pick up
shells: 2, then 8, then 8 — not drawn to scale

What you are building

further from the nucleus = higher energy level + electron

AQA onlyWhat's happening

Edexcel students: electrons and energy levels are not on your specification.

the whole atom — radius about 1 × 10⁻¹⁰ m the nucleus is in here nucleus
Zoom ×1

Why the diagrams lie

Learn the two numbers: atom radius ≈ 1 × 10⁻¹⁰ m, nucleus radius ≈ 1 × 10⁻¹⁴ m — the nucleus is about 10 000 times smaller, and yet almost all the mass is in it.

Shells are drawn evenly spaced so they fit on screen. Real energy levels get closer together further out.

▲ Protons and neutrons only go in the nucleus, electrons only on the shells — the animation won't let you put them anywhere else.

Built one? Now learn to describe it.

The exam asks you to describe the structure of an atom in words, work out particle numbers from the two numbers in the symbol, and explain why two isotopes are still the same element. The notes below do all three.

Read the notes ↓
✎

Revision notes

What an atom is made of

Every atom has a tiny central nucleus containing protons and neutrons, with electrons moving around it in shells (energy levels).

⭐ Key fact — charges and masses

ParticleRelative chargeRelative massWhere it is
Proton+11In the nucleus
Neutron01In the nucleus
Electron−1very small (about 1/2000)In shells around the nucleus

The nucleus is positive, because it holds the protons and the neutrons are neutral.

Why an atom has no overall charge

An atom has the same number of protons as electrons. Each proton is +1 and each electron is −1, so the charges cancel and the atom is neutral overall.

How big is an atom?

  • The radius of an atom is about 1 × 10⁻¹⁰ m.
  • The radius of the nucleus is less than 1/10 000 of the radius of the atom — about 1 × 10⁻¹⁴ m.
  • Almost all of the mass of the atom is in the nucleus.

💡 Exam tip

If a question asks you to compare the nucleus with the atom, quote the numbers: atom ≈ 1 × 10⁻¹⁰ m, nucleus ≈ 1 × 10⁻¹⁴ m, so the nucleus is about 10 000 times smaller. Tab 3 of the animation shows what that really looks like.

The two numbers in the symbol

Every element is written with two numbers. The bottom one is small and the top one is big — that is how you remember which is which.

NameWhereWhat it tells you
Atomic numberbottomThe number of protons. This is what defines the element — i.e. 6 protons, the element is always carbon.
Mass numbertopThe number of protons + neutrons.

So: neutrons = mass number − atomic number, and in a neutral atom electrons = protons = atomic number.

EdexcelEdexcel also uses the other names: atomic number = proton number, and mass number = nucleon number (a nucleon is any particle in the nucleus: a proton or a neutron). You must recognise both names in a question.

Isotopes

⭐ Definition

Isotopes are atoms of the same element with the same number of protons but a different number of neutrons.

Carbon always has 6 protons — that is what makes it carbon. Its isotopes differ only in neutrons:

IsotopeProtonsNeutronsElectrons
Carbon-12666
Carbon-13676
Carbon-14686

Because they all have 6 protons, they are all carbon, and they all have 6 electrons, so they are all neutral.

Ions

An ion is formed when an atom loses or gains an electron. The number of protons never changes — if it did, it would be a different element.

In GCSE physics we only consider positive ions, where an atom has lost an electron.

  • Loses an electron → more protons than electrons → a positive ion.

AQA onlyElectrons and energy levels

Edexcel students: this part is not on your specification, so you can skip to the exam questions below. It does help to explain why radiation is called “ionising”.

Electrons sit at different distances from the nucleus. Each distance is an energy level, and the ones further out are higher energy levels. Electrons can change level, and this is where the exam wants exact wording:

⭐ The two sentences to learn

An electron that absorbs electromagnetic radiation moves to a higher energy level, further from the nucleus.

An electron that falls to a lower energy level, closer to the nucleus, emits electromagnetic radiation.

If an electron absorbs enough energy it can leave the atom altogether. The atom has lost a negative charge, so it becomes a positive ion — that is what we mean by ionising radiation. Try the high-energy photon on tab 2.

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How it comes up in the exam

Nearly every question on this spec point is one of two jobs: read the numbers off a symbol, or describe a structure in words. Here is one of each.

In either case, say it explicitly: the number of protons defines the element. Examiners want that sentence written down, not implied.

Worked example · lithium-7

Lithium-7 is written with mass number 7 and atomic number 3. Give the number of protons, neutrons and electrons.

  • Protons = 3 — the atomic number, the bottom number.
  • Neutrons = 4 — mass number − atomic number = 7 − 3.
  • Electrons = 3 — the same as the protons, because the atom is neutral.

Check it: build lithium-7 on tab 1 of the animation and the symbol fills itself in as you go.

Exam-style question · 5 marks

Carbon-12 and carbon-14 are both isotopes of carbon. Describe the structure of a carbon-14 atom, and explain why carbon-12 and carbon-14 are both still carbon.

Mark scheme:

  • The nucleus contains protons and neutrons; the electrons orbit around it in shells / energy levels (1)
  • Carbon-14 has 6 protons — the atomic number (1)
  • and 8 neutrons (14 − 6) (1)
  • and 6 electrons, equal to the number of protons, so the atom is neutral overall (1)
  • Both isotopes have the same number of protons, and the number of protons is what defines the element — so both are carbon. They differ only in the number of neutrons (1)

Where marks go missing: forgetting to say the atom is neutral because the number of electrons equals the number of protons — and say why that works: electrons are negatively charged and protons are positively charged, so the charges cancel.

📘 Now do it in your workbook

Label the three carbon isotopes, fill in the lithium-7 table, draw your own atom with radiation being absorbed or emitted, then write the 5-mark carbon-14 answer and mark it yourself.

Label the three carbon isotopes and write their symbols, draw any atom you like and fill in its numbers, then write the 5-mark carbon-14 answer and mark it yourself.

AQA GCSE Physics Workbook · ATOMIC STRUCTURE · page 3 Edexcel iGCSE Physics Workbook · RADIOACTIVITY AND PARTICLES · page 4

The full workbook covers the whole of Topic 4 Atomic Structure, with exam-style questions and worked answers.

The full workbook covers the whole of Section 7 Radioactivity and Particles, with exam-style questions and worked answers.

✅ Can you do it? Tick as you go

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🎉 Nice work! You've ticked off every objective for this spec point. Don't forget to hit “Mark complete” at the bottom of the lesson.
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Prefer to watch? Here's the whole thing

Video walkthrough — coming soon

Everything above, explained out loud — useful for a last-minute recap, or if you'd rather hear it than read it.

Everything above, explained out loud — useful for a last-minute recap, or if you'd rather hear it than read it. The video is on its way.

🎬

Video coming soon

The walkthrough for this lesson is being filmed and will appear right here. Until then, the animation and the notes above cover every mark.

Now put it into practice

Page 3 of the workbook has the three carbon isotopes to label, the lithium-7 table to fill in, and the 5-mark carbon-14 question with its mark scheme.

Page 4 of the workbook has the three carbon isotopes to label, an atom of your own to draw, and the 5-mark carbon-14 question. It's free below.

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